TY - JOUR AU - Talavera Nevado, María AU - Bolaño García, Sandra AU - Bravo Bernárdez, Jorge AU - Castro Fojo, Jesús Antonio AU - García Fontán, Maria Soledad AU - Hermida Ramón, José Manuel PY - 2013 SN - 02767333 SN - 15206041 UR - http://hdl.handle.net/11093/7408 AB - The iridium methoxycarbene [IrCpCl{C(OMe)CHCPh2}(PPh2Me)]PF6 (3) can undergo a clean attack by nucleophiles at least by two different pathways: (1) an unusual nucleophilic attack of primary, secondary, and tertiary amines at the sp3 carbon–oxygen... LA - eng PB - Organometallics TI - Nucleophilic Attack in Methoxycarbenes: Heterolytic Cleavage of the Carbon (sp 3 )–Oxygen Bond versus Aminolysis DO - 10.1021/om400565c ER -