RT Journal Article
T1 Chemoselectivity on the synthesis of iridacycles: A theoretical and experimental study
A1 Pereira Cameselle, Raquel
A1 Peña Gallego, Maria De Los Angeles
A1 Cid Seara, Krystal Mar
A1 Alonso Gómez, José Lorenzo
A1 Talavera Nevado, María
A1 Bolaño García, Sandra
K1 2303.21 Compuestos Organometálicos
AB The selective synthesis of a spirobifluorene-iridacyclopentadiene complex has been achieved through the corresponding methoxyalkenylcarbeneiridium complex. The chemoselectivity of the Csingle bondH bond activation over the precursor has been studied via DFT calculations on the relative energies of the E and Z isomers of several examples and compared with experimental results. The data suggest that the steric effect of the substituents has more influence than their electronic character on the structure of the resulting iridacycle compounds.
PB Inorganica Chimica Acta
SN 00201693
YR 2021
FD 2021-03-01
LK http://hdl.handle.net/11093/7434
UL http://hdl.handle.net/11093/7434
LA eng
NO Inorganica Chimica Acta, 517, 120189 (2021)
NO Xunta de Galicia | Ref. ED431F 2016/005
DS Investigo
RD 24-mar-2025