RT Journal Article
T1 [IrCp*(NCMe)
 2
 (PPh
 2
 Me)][PF
 6
 ]
 2
 as Catalyst for the Meyer–Schuster Rearrangement of Arylpropargylic Alcohols under Mild Conditions
A1 Talavera Nevado, María
A1 Bravo Bernárdez, Jorge
A1 Gonsalvi, Luca
A1 Peruzzini, Maurizio
A1 Zuccaccia, Cristiano
A1 Bolaño García, Sandra
K1 2303 Química Inorgánica
AB The novel iridium complex [IrCp*(NCMe)2(PPh2Me)][PF6]2 (I) efficiently catalyzed the Meyer–Schuster rearrangement of selected arylpropargylic alcohols into α,β-unsaturated aldehydes under mild conditions and without the need of a co-catalyst. A mechanism involving a (hydroxy)alkenylcarbene intermediate is proposed.
PB European Journal of Inorganic Chemistry
SN 14341948
YR 2014
FD 2014-11-25
LK http://hdl.handle.net/11093/7418
UL http://hdl.handle.net/11093/7418
LA eng
NO European Journal of Inorganic Chemistry, 2014(36): 6268-6274 (2014)
DS Investigo
RD 28-abr-2025