RT Journal Article
T1 Cyclometalated Iridium Complexes from Intramolecular C–H Activation of [IrCp*Cl{═C(OMe)CH═C(CH3)R}L] (R = CH3, Ph; L = PPh2Me, PMe3)
A1 Talavera Nevado, María
A1 Bolaño García, Sandra
A1 Bravo Bernárdez, Jorge
A1 Castro Fojo, Jesús Antonio
A1 García Fontán, Maria Soledad
K1 23 Química
AB The (methoxy)alkenylcarbeneiridium complexes [IrCp*Cl{═C(OMe)CH═CR1R2}L]PF6 (R1 = CH3, R2 = CH3, Ph; R1 = Ph, R2= H; L = PPh2Me, PMe3) can undergo an intramolecular C–H activation of one of the substituents R of the alkenyl fragment to give new five-membered-ring cyclometalated iridium complexes. In this work it is shown that the arrangement of substituents in the alkenyl fragment determines the size of the ring in the iridacycle complexes. The iridacyclopenta-1,3-diene complexes [tiebar above startIrCp*{═C(OMe)CH═CRtiebar above endCH2}L]PF6 (L = PPh2Me, R = CH3 (2a), Ph (4a); L = PMe3, R = CH3 (2b), Ph (4b)) can be deprotonated to give the iridacyclopenta-2,4-diene complexes [tiebar above startIrCp*{C(OMe)═CHCR═tiebar above endCH}L] (L = PPh2Me, R = CH3 (6a), Ph (7a); L = PMe3, R = CH3 (6b), Ph (7b))
PB Organometallics
SN 02767333
YR 2013
FD 2013-11-04
LK http://hdl.handle.net/11093/7413
UL http://hdl.handle.net/11093/7413
LA eng
NO Organometallics, 32(23): 6851-7244 (2013)
DS Investigo
RD 25-ene-2025