RT Journal Article
T1 Photochemically driven tandem process in the construction of a biscyclopropylcage from 2,5-dimethoxy-p-benzoquinone and terminal acetylenes
A1 Alvarez Garcia, Jonathan
A1 Rubio Pisabarro, Víctor
A1 Silva López, Carlos
A1 Cid Fernández, María Magdalena
K1 2306.15 Mecanismos de Reacción
AB A photochemical two-step one-pot synthesis of novel biscyclopropyl-box-shaped compounds via the reaction of 2,5-dimethoxy-para-benzoquinone and monosubstituted alkynes is reported. The reaction mechanism for a process in which six new C–C bonds are formed is explored by means of experimental and computational techniques. The whole process occurs with complete selectivity, and only one densely decorated diastereomer is obtained; such a degree of control and substitution makes for a rather powerful and complexity-building process.
PB Organic Letters
SN 15237060
YR 2020
FD 2020-06-05
LK http://hdl.handle.net/11093/5788
UL http://hdl.handle.net/11093/5788
LA eng
NO Organic Letters, 22(11): 4527-4531 (2020)
NO Agencia Estatal de Investigación | Ref. CTQ2017-85919-R
DS Investigo
RD 04-dic-2024