RT Journal Article
T1 Organosolv processing of vine shoots: fractionation and conversion of hemicellulosic sugars into platform chemicals by microwave irradiation
A1 Rivas Siota, Sandra
A1 Lopez Caamaño, Laura
A1 Vila Babarro, Carlos
A1 Parajó Liñares, Juan Carlos
K1 3302.90 Ingeniería Bioquímica
K1 3303.03 Procesos Químicos
AB Vine shoots were subjected to a mild aqueous extraction (to remove water-soluble extractives), and the extracted solids were reacted in catalyzed media (containing water and 1-butanol) to achieve the one-stage solubilization of lignin and hemicelluloses, yielding a cellulose-rich solid. Operating in a microwave-heated reactor under optimized conditions (190 °C in media containing 2% of catalyst and 52% 1-butanol), 67.8% lignin was dissolved, and solids containing 75% cellulose were obtained. Lignin was recovered from the reaction medium and characterized, whereas the hemicellulose-derived products present in the aqueous phase (obtained under conditions leading to maximum concentrations of 17.7 g pentoses/L) were converted into furfural at 64.6% molar yield by acidic processing in the presence of recycled 1-butanol.
PB Bioresource Technology
SN 09608524
YR 2021
FD 2021-12
LK http://hdl.handle.net/11093/2564
UL http://hdl.handle.net/11093/2564
LA eng
NO Bioresource Technology, 342, 125967 (2021)
NO Financiado para publicación en acceso aberto: Universidade de Vigo/CISUG
NO Deputación de Ourense | Ref. INOU20-03A
DS Investigo
RD 20-abr-2025