DATE: 2018
UNIVERSAL IDENTIFIER: http://hdl.handle.net/11093/7429
EDITED VERSION: https://xlink.rsc.org/?DOI=C8CC06443A
UNESCO SUBJECT: 2307 Química Física ; 2303 Química Inorgánica
DOCUMENT TYPE: article

ABSTRACT

Synthesis of stable irida-binaphthyl and -phenanthryl complexes, the first examples of metallaaromatic biaryl atropisomers, has been achieved. The combination of experimental and theoretical studies revealed that the nature of these systems is comparable to that of well-known 1,1′-binaphthalene both in terms of aromaticity and atropisomerism.
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