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[IrCp*(NCMe) 2 (PPh 2 Me)][PF 6 ] 2 as Catalyst for the Meyer–Schuster Rearrangement of Arylpropargylic Alcohols under Mild Conditions

dc.contributor.authorTalavera Nevado, María 
dc.contributor.authorBravo Bernárdez, Jorge 
dc.contributor.authorGonsalvi, Luca
dc.contributor.authorPeruzzini, Maurizio
dc.contributor.authorZuccaccia, Cristiano
dc.contributor.authorBolaño García, Sandra 
dc.date.accessioned2024-09-13T12:31:57Z
dc.date.available2024-09-13T12:31:57Z
dc.date.issued2014-11-25
dc.identifier.citationEuropean Journal of Inorganic Chemistry, 2014(36): 6268-6274 (2014)spa
dc.identifier.issn14341948
dc.identifier.issn10990682
dc.identifier.urihttp://hdl.handle.net/11093/7418
dc.description.abstractThe novel iridium complex [IrCp*(NCMe)2(PPh2Me)][PF6]2 (I) efficiently catalyzed the Meyer–Schuster rearrangement of selected arylpropargylic alcohols into α,β-unsaturated aldehydes under mild conditions and without the need of a co-catalyst. A mechanism involving a (hydroxy)alkenylcarbene intermediate is proposed.en
dc.language.isoengspa
dc.publisherEuropean Journal of Inorganic Chemistryspa
dc.rightsCopyright © 2014 WILEY-VCH Verlag GmbH & Co
dc.title[IrCp*(NCMe) 2 (PPh 2 Me)][PF 6 ] 2 as Catalyst for the Meyer–Schuster Rearrangement of Arylpropargylic Alcohols under Mild Conditionsen
dc.typearticlespa
dc.rights.accessRightsopenAccessspa
dc.identifier.doi10.1002/ejic.201402882
dc.identifier.editorhttps://chemistry-europe.onlinelibrary.wiley.com/doi/10.1002/ejic.201402882spa
dc.publisher.departamentoQuímica inorgánicaspa
dc.publisher.grupoinvestigacionNovos Materiaisspa
dc.subject.unesco2303 Química Inorgánicaspa
dc.date.updated2024-08-22T10:32:03Z
dc.computerCitationpub_title=European Journal of Inorganic Chemistry|volume=2014|journal_number=36|start_pag=6268|end_pag=6274spa


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