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Photochemically driven tandem process in the construction of a biscyclopropylcage from 2,5-dimethoxy-p-benzoquinone and terminal acetylenes

dc.contributor.authorAlvarez Garcia, Jonathan 
dc.contributor.authorRubio Pisabarro, Víctor 
dc.contributor.authorSilva López, Carlos 
dc.contributor.authorCid Fernández, María Magdalena 
dc.date.accessioned2024-01-24T11:47:07Z
dc.date.available2024-01-24T11:47:07Z
dc.date.issued2020-06-05
dc.identifier.citationOrganic Letters, 22(11): 4527-4531 (2020)spa
dc.identifier.issn15237060
dc.identifier.issn15237052
dc.identifier.urihttp://hdl.handle.net/11093/5788
dc.description.abstractA photochemical two-step one-pot synthesis of novel biscyclopropyl-box-shaped compounds via the reaction of 2,5-dimethoxy-para-benzoquinone and monosubstituted alkynes is reported. The reaction mechanism for a process in which six new C–C bonds are formed is explored by means of experimental and computational techniques. The whole process occurs with complete selectivity, and only one densely decorated diastereomer is obtained; such a degree of control and substitution makes for a rather powerful and complexity-building process.spa
dc.description.sponsorshipAgencia Estatal de Investigación | Ref. CTQ2017-85919-Rspa
dc.description.sponsorshipXunta de Galicia | Ref. ED431E 2018/07spa
dc.description.sponsorshipXunta de Galicia | Ref. EDC431C 2017/70spa
dc.language.isoengspa
dc.publisherOrganic Lettersspa
dc.relationinfo:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2013-2016/CTQ2017-85919-R/ES/RECONOCIMIENTO SUPRAMOLECULAR HELICOIDAL: COMPLEJOS HOSTGUEST RIGIDOS Y SISTEMAS MOLECULARES AUTO-ENSAMBLADOS
dc.rights© 2020 American Chemical Society
dc.titlePhotochemically driven tandem process in the construction of a biscyclopropylcage from 2,5-dimethoxy-p-benzoquinone and terminal acetyleneseng
dc.typearticlespa
dc.rights.accessRightsopenAccessspa
dc.identifier.doi10.1021/acs.orglett.0c01554
dc.identifier.editorhttps://doi.org/10.1021/acs.orglett.0c01554spa
dc.publisher.departamentoQuímica orgánicaspa
dc.publisher.grupoinvestigacionSíntese, Estructura e Simulación (S3)spa
dc.subject.unesco2306.15 Mecanismos de Reacciónspa
dc.date.updated2024-01-22T10:52:04Z
dc.computerCitationpub_title=Organic Letters|volume=22|journal_number=11|start_pag=4527|end_pag=4531spa
dc.referencesThis document is the Accepted Manuscript version of a Published Work that appeared in final form in Organic Letters, copyright © 2020 American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see: https://doi.org/10.1021/acs.orglett.0c01554


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