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dc.contributor.authorMiguez Lago, Sandra 
dc.contributor.authorGliemann, Bettina D.
dc.contributor.authorKivala, Milan
dc.contributor.authorCid Fernandez, María Magdalena 
dc.date.accessioned2022-09-13T11:37:40Z
dc.date.available2022-09-13T11:37:40Z
dc.date.issued2021-09-20
dc.identifier.citationChemistry - A European Journal, 27(53): 13352-13357 (2021)spa
dc.identifier.issn09476539
dc.identifier.issn15213765
dc.identifier.urihttp://hdl.handle.net/11093/3819
dc.descriptionFinanciado para publicación en acceso aberto: Universidade de Vigo/CISUG
dc.description.abstractChirality, a characteristic tool of molecular recognition in nature, is often a complement of redox active systems. Scientists, in their eagerness to mimic such sophistication, have designed numerous chiral systems based on molecular entities with cavities, such as macrocycles and cages. In an attempt to combine chirality and redox-active species, in this contribution we report the synthesis and detailed characterization of a chiral shape-persistent molecular cage based on the combination of enantiopure diethynylallenes and electron-rich bridged triarylamines, also known as N-heterotriangulenes. Its ability for chiral recognition in solution was revealed through UV/vis titrations with enantiopure helicenes.spa
dc.description.sponsorshipAgencia Estatal de Investigación | Ref. CTQ2017-85919-Rspa
dc.description.sponsorshipDeutsche Forschungsgemeinschaft | Ref. 182849149spa
dc.description.sponsorshipDeutsche Forschungsgemeinschaft | Ref. 281029004-SFB1249spa
dc.description.sponsorshipFP7 People: Marie-Curie Actions | Ref. PIRSES-GA-2012-318930-InTechSEspa
dc.description.sponsorshipXunta de Galicia | Ref. ED431C 2017/70spa
dc.language.isoengspa
dc.publisherChemistry - A European Journalspa
dc.relationinfo:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2013-2016/CTQ2017-85919-R/ES/RECONOCIMIENTO SUPRAMOLECULAR HELICOIDAL: COMPLEJOS HOSTGUEST RIGIDOS Y SISTEMAS MOLECULARES AUTO-ENSAMBLADOS
dc.rightsAttribution-NonCommercial 4.0 International
dc.rights.urihttps://creativecommons.org/licenses/by-nc/4.0/
dc.titleA chiral molecular cage comprising diethynylallenes and N‐heterotriangulenes for enantioselective recognitionen
dc.typearticlespa
dc.rights.accessRightsopenAccessspa
dc.identifier.doi10.1002/chem.202101801
dc.identifier.editorhttps://onlinelibrary.wiley.com/doi/10.1002/chem.202101801spa
dc.publisher.departamentoQuímica orgánicaspa
dc.publisher.grupoinvestigacionSíntese, Estructura e Simulación (S3)spa
dc.subject.unesco2306 Química Orgánica
dc.date.updated2022-08-29T11:04:45Z
dc.computerCitationpub_title=Chemistry - A European Journal|volume=27|journal_number=53|start_pag=13352|end_pag=13357spa


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