Influence of water and ethanol in the physical properties of choline glycinate at several temperatures
DATE:
2022-10
UNIVERSAL IDENTIFIER: http://hdl.handle.net/11093/3797
EDITED VERSION: https://linkinghub.elsevier.com/retrieve/pii/S0167732222015604
UNESCO SUBJECT: 3303.90 Tensioactivos ; 2213.09 Equilibrios Termodinámico ; 3308.07 Eliminación de Residuos
DOCUMENT TYPE: article
ABSTRACT
In this study, a physical characterization (density (q), refractive index (nD), speed of sound (u) and
dynamic viscosity (g)) as a function of temperature (298.15–343.15 K) of choline glycinate (ChGly) and
its binary mixtures with water or/and methanol over the entire composition range was performed from
298.15 K to 323.15 K. Several derived properties of the pure ionic liquid and excess molar volume (VE
m) changes of refractive index on mixing (DnD), deviations in isentropic compressibility (DjS) and viscosity
deviations (Dg) have been calculated using the experimental data in the selected temperature range.
These experimental data of ChGly have been positively correlated using polynomial equations and the
derived magnitudes were successfully fitted to Redlich-Kister equation. Finally, different models have
been implemented for the first time to predict the density of the selected binary mixtures as a function
of the temperature.